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Publikationen 2005 - 2008



Lithiation of TMEDA and its Higher Homologous TEEDA: Understanding Observed α- and β-Deprotonation:
V.H. Gessner, C. Strohmann: J. Am. Chem. Soc. 2008, 130, 14412-14413. pdf


A precoordination complex of 1,2,3-trimethyl-1,3,5-triazacyclohexane with tert-buthyllithium as key intermediate in its methylene group deprotonation:
C. Strohmann, V.H. Gessner: Chem. Asian J. 2008, 3, 1929-1934. pdf


Isopropyllithium Diamine Adducts: From a Non Symmetric Aggregate to Monomeric i-PrLi·(1R,2R)-N,N,N',N'-Tetraethylcyclohexane-1,2-diamine:
C. Strohmann, V.H. Gessner, A. Damme, Chem. Commun. 2008, 3381-3383.


Structure/Reactivity Studies on an α-Lithiated Benzylsilane: Chemical Interpretation of Experimental Charge Density:
H. Ott, C. Däschlein, D. Leusser, D. Schildbach, T. Seibel, D. Stalke, C. Strohmann, J. Am. Chem. Soc. 2008, 130, 11901-11911. pdf


Bent Phenyl Groups in Lithiosilanes – Crystal Structures and Interpretation of this Unanticipated Feature:
C. Strohmann, C. Däschlein, Chem. Commun. 2008, 2791-2793. pdf


(S)-1,2-Dimethyl-1,1,2-triphenyl-2-(4-piperidiniomethyl)disilane chloride:
C. Däschlein, V.H. Gessner, C. Strohmann, Acta Cryst. E 2008, 64, o1950. pdf


C. Strohmann, V.H. Gessner, A. Damme, S. Koller, C. Däschlein, Acta Cryst. E 2008, 64, o687. pdf


Synthesis and Reactivity of Silylated Tetrathiafulvalenes:
A. Hameau, F. Guyon, M. Knorr, C. Däschlein, C. Strohmann, N. Avarvari, Dalton Trans. 2008, 4866-4876. pdf


Crystal Structures of n-BuLi Adducts with (R,R)-TMCDA and the Consequences for the Deprotonation of Benzene:
C. Strohmann, V.H. Gessner, J. Am. Chem. Soc. 2008, 130, 11719-11725. pdf


Syntheses, Structures, and Photophysical Properties of Mono- and Dinuclear Sulfur-Rich Gold(I) Complexes:
F. Guyon, A. Hameau, A. Khatyr, M. Knorr, H. Amrouche, D. Fortin, P.D. Harvey, C. Strohmann, A.L. Ndiaye, V. Huch, M. Veith, N. Avarvari, Inorg. Chem. 2008, 47, 7483-7492. pdf


Synthesis of a Highly Enantiomerically Enriched Silagermane and Selective Cleavage of the Si–Ge Bond with Lithium:
C. Strohmann, C. Däschlein, Organometallics 2008, 27, 2499-2504. pdf


Silver-Catalyzed Spirolactonization: First Synthesis of Spiroisoindole-γ-Methylene-γ-Butyrolactones:
M.M. Rammah, M. Othman, K. Ciamala, C. Strohmann, M.B. Rammah, Tetrahedron 2008, 64, 3505-3516. pdf



111. Von monomerem tBuLi·(R,R)-TMCDA zu α-lithiiertem (R,R)-TMCDA:
C. Strohmann, V.H. Gessner, Angew. Chem. 2007, 119, 8429-8432. pdf
110. Crystal Structures of the Chiral Diamine (R,R)-TMCDA with the Commonly Used Alkyllithium Bases Methyllithium, iso-Propyllithium and sec-Butyllithium:
C. Strohmann, V.H. Gessner, J. Am. Chem. Soc. 2007, 129, 8952-8953. pdf
109. Von dem Alkyllithium-Aggregat [(n-BuLi)2·PMDTA]2 zu lithiiertem PMDTA:
C. Strohmann, V.H. Gessner, Angew. Chem. 2007, 119, 4650-4653. pdf
108. Ein hoch enantiomerenangereichertes Lithiosilan durch selektive Spaltung einer Silicium-Phenyl-Bindung mit Lithium:
C. Strohmann, C. Däschlein, M. Kellert, D. Auer, Angew. Chem. 2007, 119, 4864-4866. pdf
107. (2,2-Dibromovinyl)ferrocene as a building block for the assembly of heterodinuclear complexes – Preparation of an σ-alkenylpalladium complex and dimetallic dithioether complexes:
S. Clement, L. Guyard, M. Knorr, F. Villafañe, C. Strohmann, M.M. Kubicki, Eur. J. Inorg. Chem. 2007, 5052-5061. pdf
106. {[(C7H7LiO)6·(thf)2·(µ-diglyme-kO,kO')]Li2O}: a µ6-O2- ion encapsulating aryllithium compound:
C. Strohmann, V.H. Gessner, Z. Anorg. Allg. Chem. 2007, 633, 2285-2287. pdf
105. Ethynyl[2.2]paracyclophanes and 4-isocyano[2.2]paracyclophanes as ligands in organometallic chemistry:
S. Clément, L. Guyard, M. Knorr, S. Dilsky, C. Strohmann, M. Arroyo, J. Organomet. Chem. 2007, 692, 839-850. pdf
104. Synthesis of Some Spirochroman-4-Ones by Regioselective [4+2] Cycloaddition Reactions:
M. Askri, M. Rammah, K. Monnier-Jobé, K. Ciamala, M. Knorr, C. Strohmann, Lett. Org. Chem. 2007, 4, 222-227.
103. Construction of 1D and 2D Copper(I) Coordination Polymers Assembled by PhS(CH2)nSPh (n = 1, 2) Dithioether Ligands: Surprising Effect of the Spacer Length on the Dimensionality, ClusterNuclearity and the Fluorescence Properties of the Metal-organic Framework:
H.N. Peindy, F. Guyon, A. Khatyr, M. Knorr, C. Strohmann, Eur. J. Inorg. Chem. 2007, 1823-1828. pdf



102. A Monolithiated and Its Related 1,3-Dilithiated Allylsilane: Syntheses, Crystal Structures, and Reactivity:
C. Strohmann, K. Lehmen, S. Dilsky, J. Am. Chem. Soc., 2006, 128, 8102-8103. pdf
101. Insertion Reactions of Alkynes and Organic Isocyanides into the Palladium-Carbon Bond of Dimetallic Fe-Pd Alkoxysilyl Complexes:
M. Knorr, I. Jourdain, P. Braunstein, C. Strohmann, A. Tiripicchio, F. Ugozzoli, Dalton Trans. 2006, 5248-5258. pdf
100. Crystal Structures of the Chiral Lithiosilanes [(Lis)-PhMe2SiLi·THF·(–)-Sparteine] and [Ph2(NEt2)SiLi·(–)-Sparteine]:
C. Strohmann, C. Däschlein, D. Auer, J. Am. Chem. Soc. 2006, 128, 704-705. pdf
99. Self-assembly of Dithiolene-based Coordination Polymers of Mercury(II). Dithioether versus Thiocarbonyl bonding:
A. Hameau, F. Guyon, M. Knorr, M. Enescu, C. Strohmann, Monatsh. Chem. 2006, 137, 545-555. pdf
98. Crystal Structures of [PhLi·(-)-sparteine]2, [PhOLi·(-)-sparteine]2 and the Mixed Aggregate [PhLi·PhOLi·2 (-)-sparteine]:
C. Strohmann, S. Dilsky, K. Strohfeldt, Organometallics 2006, 25, 41-44. pdf
97. Reactivity of silyl-substituted heterobimetallic iron-platinum hydride complexes: Part III. Alkyne insertions into the platinum-hydride bond and competition between µ-vinylidene and dimetallacyclopentenone formation:
I. Jourdain, L. Vieille-Petit, S. Clement, M. Knorr, F. Villafañe, C. Strohmann, Inorg. Chem. Commun. 2006, 9, 127-131. pdf
96. 1,1,2,2-Tetramethyl-1,2-bis(phenylthiomethyl)disilane, a Flexible Ligand for the Construction of Macrocyclic, Mesocyclic and Bridged Dithioether Complexes. Synthesis of the Bis-silylated Olefins Z-(PhSCH2)Me2SiC(H):C(Ar)SiMe2(CH2SPh) by Catalytic Activation of the Si-Si Bond:
H.N. Peindy, F. Guyon, I. Jourdain, M. Knorr, D. Schildbach, C. Strohmann, Organometallics 2006, 25, 1472-1479. pdf
95. Chemistry and Electrochemistry of the Heterodinuclear Complex ClPd(dppm)2PtCl Bond Providing Site Selectivity:
D. Evrard, S. Clement, D. Lucas, B. Hanquet, M. Knorr, C. Strohmann, A. Decken, Y. Mugnier, P.D. Harvey, Inorg. Chem. 2006, 45, 1305-1315. pdf



94. Understanding Substituent Effects on 29Si Chemical Shifts an Bonding in Disilynes. A Quantum Chemical Analysis:
D. Auer, M. Kaupp, C. Strohmann, Organometallics 2005, 24, 6331-6337. pdf
93. Selective Si–C Bond Cleavage as Synthetic Entry to a Functionalized Lithiosilane:
C. Strohmann, D. Schildbach, D. Auer, J. Am. Chem. Soc. 2005, 127, 7968-7969. pdf
92. Complexation of 1,4-Bis(phenylthio)butane on Mercury(II) Salts: Formation of Extended 2D Coordination Polymers:
H.N. Peindy, F. Guyon, M. Knorr, C. Strohmann, Z. Anorg. Allg. Chem. 2005, 631, 2397-2400. pdf
91. Formation of Extended 1D Coordination Polymers in Tetrathioether Complexes of Mercury(II): Effect of the Organic Substituents on the Crystal Structures of {Si(CH2SR)4}HgBr2 (R = Me, Ph):
H.N. Peindy, F. Guyon, M. Knorr, A.B. Smith, J.A. Farouq, S.A. Islas, D. Rabinovich, J.A. Golen, C. Strohmann, Inorg. Chem. Commun. 2005, 8, 479-482. pdf
90. Reactivity of Silyl-substituted Heterobimetallic Iron-Platinum Hydride Complexes towards Unsaturated Molecules: Part II. Insertion of Trifluoropropyne and Hexafluorobutyne into the Platinum-Hydride Bond:
M. Knorr, I. Jourdain, F. Villafañe, C. Strohmann, J. Organomet. Chem. 2005, 690, 1456-1466. pdf
89. Ein hoch diastereomerenangereichertes Lithiumalkyl, konfigurationsstabil bei Raum-temperatur: Darstellung, Molekülstruktur und der diastereodivergente stereo-chemische Reaktionsverlauf in Abhängigkeit des Solvens:
C. Strohmann, B.C. Abele, K. Lehmen, D. Schildbach, Angew. Chem. 2005, 117, 3196-3199. pdf
88. An Enantiomerically Enriched Silyllithium Compound: The Stereochemical Course of its Transformations:
J. Hörnig, D. Auer, M. Bindl, V.C. Fraaß, C. Strohmann in Organosilicon Chemistry VI (Hrsg.: N. Auner, J. Weis), VCH, Weinheim, 2005, S. 502-507.
87. Diastereomerically Enriched α-Lithiated Benzylsilanes:
D. Schildbach, M. Bindl, J. Hörnig, C. Strohmann
in Organosilicon Chemistry VI (Hrsg.: N. Auner, J. Weis), VCH, Weinheim, 2005, S. 495-501.
86. Synthesis and Reactivity of an Enantiomerically Pure N-Methyl-2-silyl Substituted Pyrrolidine,
K. Strohfeldt, T. Seibel, P. Wich, C. Strohmann in Organosilicon Chemistry VI (Hrsg.: N. Auner, J. Weis), VCH, Weinheim, 2005, S. 488-494.



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